Abstract.
In weakly acidic buffer medium, vitamin B1 (VB1) interacts with gold nanoparticles to form a binding product, which resulted in a significant enhancement of resonance Rayleigh scattering (RRS) intensity and the appearance of a new RRS spectrum. The maximum RRS peak was at 368 nm, and there are three smaller scattering peaks that were at 284 nm, 440 nm and 495 nm, respectively. The enhanced RRS intensity (ΔI) was directly proportional to the concentration of VB1 in the range of 0–2.8 × 10−7 mol L−1. The method had high sensitivity and its detection limit (3σ) was 0.9 ng mL−1. The optimum conditions and the influencing factors have been investigated. The method had good selectivity, which could be observed from the influence of coexisting substances. A sensitive, simple and fast RRS method for the determination of VB1 with gold nanoparticle probe has been developed. In addition, the reasons for RRS enhancement were discussed.
Similar content being viewed by others
References
H Fujiwara S Yanagida P V Kamat (1999) J Phys Chem B 103 2589 Occurrence Handle1:CAS:528:DyaK1MXhvFSjtLg%3D
H Imahori M Arimura T Hanada Y Nishimura I Yamazaki Y Sakata S Fukuzumi (2001) J Am Chem Soc 123 335 Occurrence Handle1:CAS:528:DC%2BD3cXoslGrsb8%3D
A K Boal V M Rotello (1999) J Am Chem Soc 121 4914 Occurrence Handle10.1021/ja9905288 Occurrence Handle1:CAS:528:DyaK1MXivVarsb4%3D
A C Templeton D E Cliffel R W Murray (1999) J Am Chem Soc 121 7081 Occurrence Handle10.1021/ja990513+ Occurrence Handle1:CAS:528:DyaK1MXktlKlur8%3D
O V Makarova A E Ostafin H Miyoshi J R Norris J D Meisel (1999) Phys Chem B 103 9080 Occurrence Handle1:CAS:528:DyaK1MXisVGgsro%3D
S Y Lin S W Liu C M Lin C M Chen (2002) Anal Chem 74 330 Occurrence Handle1:CAS:528:DC%2BD3MXovFalsb0%3D
C A Mirkin R L Letsinger R C Mucis J J Storhoff (1996) Nature 382 607 Occurrence Handle10.1038/382607a0 Occurrence Handle1:CAS:528:DyaK28XltVWqsrk%3D
R C Mucis J J Storhoff C A Mirkin R L Letsinger (1998) J Am Chem Soc 120 12674
C A Mirkin R L Letsinger (2000) Science 289 175
O D Velev E W Kaler (1999) Langmuir 15 3693 Occurrence Handle10.1021/la981729c Occurrence Handle1:CAS:528:DyaK1MXis1yku7k%3D
M Lahav A N Shipway I Willner (1999) J Chem Soc Perkin Trans 2 1925
L A Lyon M D Musick M J Natan (1998) Anal Chem 70 5177 Occurrence Handle1:CAS:528:DyaK1cXntFegtrk%3D
J J Storhoff C A Mirkin (1999) Chem Rev 99 1849 Occurrence Handle10.1021/cr970071p Occurrence Handle1:CAS:528:DyaK1MXjsVarsLw%3D
C M Stoscheck (1987) Anal Biochem 160 301 Occurrence Handle10.1016/0003-2697(87)90051-0 Occurrence Handle1:CAS:528:DyaL2sXpvVynsg%3D%3D
R F Pasternack C Bustamante P J Collings A Diannetto E J Gibbs (1993) J Am Chem Soc 115 5393 Occurrence Handle10.1021/ja00066a006 Occurrence Handle1:CAS:528:DyaK3sXksVemsrs%3D
C Z Huang K A Li S Y Tong (1997) Anal Chem 69 514 Occurrence Handle1:CAS:528:DyaK2sXptVajsg%3D%3D
S P Liu X L Hu H Q Luo L Fan (2002) Sci China Ser B 32 18
S P Liu Q Liu (2001) Anal Sci 17 239 Occurrence Handle1:CAS:528:DC%2BD3MXhsVOrsr0%3D
S P Liu R Yang Q Liu (2001) Anal Sci 17 243 Occurrence Handle1:CAS:528:DC%2BD3MXhsVOrsrs%3D
S P Liu H Q Luo N B Li Z F Liu (2001) Anal Chem 76 3907
H Q Luo S P Liu Z F Liu Q Liu N B Li (2001) Anal Chim Acta 449 267 Occurrence Handle10.1016/S0003-2670(01)01365-4
X L Hu S P Liu H Q Luo (2003) Acta Chim Sinica 28 585
L Fan S P Liu D C Yang X L Hu (2002) Chinese J Chem 18 971
X L Hu S P Liu N B Li (2003) Anal Bioanal Chem 376 42 Occurrence Handle1:CAS:528:DC%2BD3sXjsVGktbk%3D
S P Liu P Feng (2002) Microchim Acta 468 275
S P Liu Z F Liu G M Zhou (1998) Anal Lett 37 1247
S P Liu Q Liu Z F Liu M Li C Z Huang (1999) Anal Chim Acta 379 53 Occurrence Handle10.1016/S0003-2670(98)00679-5
S P Liu Z F Liu (2001) Acta Chim Sinica 59 1864 Occurrence Handle1:CAS:528:DC%2BD3MXovFGqsL8%3D
Z L Jiang S P Liu L S Wang A M Qin H Liang (2003) Chem J Chinese Universities 24 1201 Occurrence Handle1:CAS:528:DC%2BD3sXmtVCitrg%3D
Z L Jiang S P Liu B G Zhao S Chen J Li (2002) Spectroscopy and Spectral Analysis 22 615 Occurrence Handle1:CAS:528:DC%2BD38XmvVyru7s%3D
S P Liu Z L Jiang L Kong Q Liu (2002) Sci China Ser B 45 616 Occurrence Handle1:CAS:528:DC%2BD38XptlKjsr0%3D
G Frens (1973) Nature Phys Sci 241 20 Occurrence Handle1:CAS:528:DyaE3sXns1ansg%3D%3D
M M Alvarez J T Khoury T G Schaaff M N Shafigullin I Vezmar R L Whetten (1997) J Phys Chem B 101 3706 Occurrence Handle10.1021/jp962922n Occurrence Handle1:CAS:528:DyaK2sXislyqsr8%3D
Q L Wang M D Chen (1995) Physical Testing and Chemical Analysis Part B: Chem Anal 31 297 Occurrence Handle1:CAS:528:DyaK2MXpvFSht78%3D
P Ortega-Barrales M L Fernández de Córdova A Molina Díaz (1998) Anal Chem 70 271 Occurrence Handle10.1021/ac9708093 Occurrence Handle1:CAS:528:DyaK2sXotVGqtLk%3D
C X Zhang G J Zhou Z J Zhang M Aizawa (1999) Anal Chim Acta 394 165 Occurrence Handle10.1016/S0003-2670(99)00293-7 Occurrence Handle1:CAS:528:DyaK1MXksFWlur8%3D
T Perez-Ruiz C Martinez-Lozano V Tomas I Ibarra (1992) Talanta 39 907 Occurrence Handle10.1016/0039-9140(92)80270-N Occurrence Handle1:CAS:528:DyaK38XlvVertr8%3D
Y M Issa A F Shoukry H Ibrahim S K Mohamed (1994) Anal Lett 27 731 Occurrence Handle1:CAS:528:DyaK2cXisFenurY%3D
Y P Ren H W Chen Q J Chen L B Bao B F Huang Q H He (2000) Chin J Anal Chem 28 554 Occurrence Handle1:CAS:528:DC%2BD3cXjvVantLw%3D
R H Huang (1998) Chin J Anal Chem 26 1355 Occurrence Handle1:CAS:528:DyaK1cXnslOltr8%3D
Z P Zhu D F Li (1992) Chin J Anal Chem 20 1360 Occurrence Handle1:CAS:528:DyaK3sXnvFGluw%3D%3D
D B Gomis L L González D G Álvarez (1999) Anal Chim Acta 396 55 Occurrence Handle10.1016/S0003-2670(99)00363-3 Occurrence Handle1:CAS:528:DyaK1MXls1yntLk%3D
A F Dănet J M Calatayud (1994) Talanta 41 2147
P Ortega-Barrales M L Fernández de Córdova A Molina Díaz (1998) Anal Chim Acta 376 227 Occurrence Handle1:CAS:528:DyaK1cXntVGjsr0%3D
Y Mrestani R H H Neubert (2000) J Chromatog A 871 351 Occurrence Handle1:CAS:528:DC%2BD3cXitVWmtbo%3D
S M Saad E Eman (1989) Analyst 114 114
Editorial Committee of the Pharmacopoeia of People’s Republic of China, The Pharmacopoeia of People’s Republic of China (Part II) (2000) Chemical Industry press, Beijing, p 785
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Liu, S., Chen, Y., Liu, Z. et al. A Highly Sensitive Resonance Rayleigh Scattering Method for the Determination of Vitamin B1 with Gold Nanoparticles Probe. Microchim Acta 154, 87–93 (2006). https://doi.org/10.1007/s00604-005-0477-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00604-005-0477-6