Preliminary communicationChemical characterization of a new 5,7-diamino-3,5,7,9-tetradeoxynonulosonic acid released by mild acid hydrolysis of the Legionella pneumophila serogroup 1 lipopolysaccharide
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A versatile de novo synthesis of legionaminic acid and 4-epi-legionaminic acid starting from D-serine
2019, Carbohydrate ResearchExploration of the Sialic Acid World
2018, Advances in Carbohydrate Chemistry and BiochemistryAnalysis of monosaccharides, fatty constituents and rare O-acetylated sialic acids from gonads of the starfish Asterias rubens
2006, BiochimieCitation Excerpt :Based on previous work [1,2], sialic acids present an extreme diversity and more than 40 different compounds were identified differing in the presence in position 5 of an amino group (neuraminic acid derivatives) or an hydroxyl group (3-deoxy-d-glycero-d-galacto-nonulosonic acid (Kdn)), different acylations of the NH2 group at position 5 (acetyl, glycolyl) and various substituents of the different hydroxyl groups (acetyl, lactyl, methyl, sulphate, phosphate, etc.). Complex monosaccharides structurally identical with sialic acids were identified in bacteria (legionaminic acid and derivatives), which may represent important epitopes [7,8]. Sialic acids show sometimes a clear species specificity.
Identification and characterization of NeuB3 from Campylobacter jejuni as a pseudaminic acid synthase
2005, Journal of Biological ChemistryStructure and serological characterization of 5,7-diamino-3,5,7,9-tetradeoxy-non-2-ulosonic acid isolated from lipopolysaccharides of Vibrio parahaemolyticus O2 and O-untypable strain KX-V212
2003, Carbohydrate ResearchCitation Excerpt :The stereoisomeric configuration of the NonlA was identified as the d-glycero-d-galacto configuration, based on 1H and 13C NMR data obtained in this study, as well as on those reported for synthetic NonlA isomers.21 Isomers of NonlA are known to distribute as constituents of O-polysaccharides in the LPSs of Gram-negative bacteria such as genus Pseudomonas,9–11,14,21Shigella,9Legionella,12,13Vibrio,15,17Acinetobactor,16Salmonella,17Yersinia19 and Proteus20. Their originally described stereoisomeric configurations have been revised22 by using chemically synthesized d-glycero-d-galacto and d-glycero-d-talo isomers.
5,7-Diamino-3,5,7,9-tetradeoxynon-2-ulosonic acids in bacterial glycopolymers: Chemistry and biochemistry
2003, Advances in Carbohydrate Chemistry and BiochemistryCitation Excerpt :A fourth sugar was found only in LPS of L. pneumophila.12,40 It was initially identified as the l-glycero-d-talo isomer12 but later revised to the d-glycero-d-talo isomer and named 4-epilegionaminic acid (4).11,40 Two more stereoisomers of the nonulosonic acids were found in several other L. pneumophila isolates40 but their configurations have not yet been determined.