Chemical Resolution at Ionic Crystal Surfaces Using Dynamic Atomic Force Microscopy with Metallic Tips

G. Teobaldi, K. Lämmle, T. Trevethan, M. Watkins, A. Schwarz, R. Wiesendanger, and A. L. Shluger
Phys. Rev. Lett. 106, 216102 – Published 25 May 2011
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Abstract

We demonstrate that well prepared and characterized Cr tips can provide atomic resolution on the bulk NaCl(001) surface with dynamic atomic force microscopy in the noncontact regime at relatively large tip-sample separations. At these conditions, the surface chemical structure can be resolved yet tip-surface instabilities are absent. Our calculations demonstrate that chemical identification is unambiguous, because the interaction is always largest above the anions. This conclusion is generally valid for other polar surfaces, and can thus provide a new practical route for straightforward interpretation of atomically resolved images.

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  • Received 3 February 2011

DOI:https://doi.org/10.1103/PhysRevLett.106.216102

© 2011 American Physical Society

Authors & Affiliations

G. Teobaldi1, K. Lämmle2, T. Trevethan3,4, M. Watkins5, A. Schwarz2,*, R. Wiesendanger2, and A. L. Shluger3,4,†

  • 1Surface Science Research Centre, Department of Chemistry, University of Liverpool, L69 3BX Liverpool, United Kingdom
  • 2Institute of Applied Physics, University of Hamburg, Jungiusstraße 11, 20355 Hamburg, Germany
  • 3Department of Physics and Astronomy, University College London, Gower Street, WC1E 6BT London, United Kingdom
  • 4WPI-AIMR, Tohoku University, 2-1-1 Katahira, Aoba, Sendai, 980-8577, Japan
  • 5The London Centre for Nanotechnology, University College London, 17-19 Gordon Street, WC1H 0AH London, United Kingdom

  • *aschwarz@physnet.uni-hamburg.de
  • a.shluger@ucl.ac.uk

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Issue

Vol. 106, Iss. 21 — 27 May 2011

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